BMS11105 - Drug Design and Chemotherapy - Medical Science Assignment Help

Assignment Task

Background: Write a background section on the link between telomerase, anthraquinones and cancer chemotherapy (supported by suitable references). This should include statements on cationic (positively-charged) side chain substituents for DNA-binding to either duplex or quadruplex DNA. Also include comments on which anthraquinone substitution patterns are preferred for G-quadruplex stabilisation.

References: List all supporting references cited in the background and R&D text, typically 6-10, in full, and in Harvard Style or similar. Numerical citations in the text are not acceptable. Complete references are required in the reference list, including all authors, year, article title, journal, volume and pages.

Results and Discussion: The t.l.c. plate in Figure 1 shows two spots, one is red and the other circled one is uv active (at 254 nm).

i. List the Rf values for both spots, showing how the Rf values were calculated. 

ii. Considering the experimental procedure for the synthesis of MSc-A, what is the likely identity of the uv active spot and why?

iii. What reagents and solvents used in the procedure for the synthesis of MSc-A would not be visible (coloured or uv active at 254 nm) on the t.l.c. plate and why?

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