Highlights
Problem set 1:
The NMR spectra Of an organic compound Of molecular formula CllH100g was recorded on 400 MHz instrument. Elucidate the structure based on the NMR spectra provided. NMR spectra provided includes IH, 13C, DEPT 135, DEPT 90, COSY and HSQC (attachment 1: Problem set 1). COSY and HSQC are provided ONLY as additional help for the assignment, inclusion in the discussion is NOT compulsory.
In your answer include:
i) IH spectral details (Chemical shift values, Coupling pattern and constants with unit, Number of proton integration and assignment Of peaks as aromatic/alkene/...etc any Other remarks) 13C spectral details (Chemical shift values, type [C, CH2, CH3] and assignment of peaks as aromatic/alkene/...etc).
2: Problem set 2). (The IH NMR and 13C NMR of starting substrate A has been provided for reference purpose only).
Substrate A
The spectra for product B was recorded on 400 MHz instrument. Elucidate the structure based on the NMR spectra provided: IH, 13C, DEPT 135, DEPT 90.
In your answer include:
i) IH spectral details (Chemical shift values, Coupling pattern and constants with unit, Number Of proton integration and assignment of peaks as aromatic/alkene/...etc and any other remarks) 13C spectral details (Chemical shift values, type [C, CH2, CH3] and assignment). Draw the proposed structure and assign IH and 13C chemical shift values with brief justification.
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