Rate of Reaction, Initial Rates & Various Concentrations Along With Rate Equation - Science & Maths Assignment Help

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Assignment Task

 

Task

1.Explain what is meant by the term "rate of reaction".

2.The initial rates of the reaction 2A + B ? 2C + D at various concentrations of A and B are given below:
[A] moldm-3    [B] moldm-3    Initial rate /moldm-3s-1
0.01    0.20    0.10
0.02    0.20     0.20
0.01    0.40    0.40


a)What is the order of reaction with respect to A and B?

b)What is the overall order of reaction?

c)What is the rate constant?

d)What will be the rate of the reaction if the concentrations of A and B are both 0.01 moldm-3?

3. For the reaction 2NO(g) + H2(g) ? N2O(g) + H2O(g), the following rate data were collected:

Initial [NO]/M    Initial [H2]/M    Initial rate/Ms-1
0.60    0.37    3.0 x 10-3
1.20    0.37    1.2 x 10-2
1.20    0.74    1.2 x 10-2

Q-What is the rate constant for the reaction?     

4.For the reaction PCl3 + Cl2 ? PCl5, the following data were obtained:
Experiment No.    [PCl3]/moldm-3    [Cl2]/ moldm-3    Rate / moldm-3s-1
1    0.36    1.26    6.0 x 10-4
2    0.36    0.63    1.5 x 10-4
3    0.72    2.52    4.8 x 10-3

Q-Deduce the rate equation and the rate constant.

 

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